Mesoporous Li3VO4/C Submicron‐Ellipsoids Supported on Reduced Graphene Oxide as Practical Anode for High‐Power Lithium‐Ion Batteries

نویسندگان

  • Qidong Li
  • Qiulong Wei
  • Jinzhi Sheng
  • Mengyu Yan
  • Liang Zhou
  • Wen Luo
  • Ruimin Sun
  • Liqiang Mai
چکیده

Despite the enormous efforts devoted to high-performance lithium-ion batteries (LIBs), the present state-of-the-art LIBs cannot meet the ever-increasing demands. With high theoretical capacity, fast ionic conductivity, and suitable charge/discharge plateaus, Li3VO4 shows great potential as the anode material for LIBs. However, it suffers from poor electronic conductivity. In this work, we present a novel composite material with mesoporous Li3VO4/C submicron-ellipsoids supported on rGO (LVO/C/rGO). The synthesized LVO/C/rGO exhibits a high reversible capacity (410 mAh g-1 at 0.25 C), excellent rate capability (230 mAh g-1 at 125 C), and outstanding long-cycle performance (82.5% capacity retention for 5000 cycles at 10 C). The impressive electrochemical performance reveals the great potential of the mesoporous LVO/C/rGO as a practical anode for high-power LIBs.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Advanced Mesoporous Spinel Li4Ti5O12/rGO Composites with Increased Surface Lithium Storage Capability for High-Power Lithium-Ion Batteries.

Spinel Li4Ti5O12 (LTO) and reduced graphene oxide (rGO) are attractive anode materials for lithium-ion batteries (LIBs) because of their unique electrochemical properties. Herein, we report a facile one-step hydrothermal method in preparation of a nanocomposite anode consisting of well-dispersed mesoporous LTO particles onto rGO. An important reaction step involves glucose as a novel linker age...

متن کامل

Photothermally reduced graphene as high-power anodes for lithium-ion batteries.

Conventional graphitic anodes in lithium-ion batteries cannot provide high-power densities due to slow diffusivity of lithium ions in the bulk electrode material. Here we report photoflash and laser-reduced free-standing graphene paper as high-rate capable anodes for lithium-ion batteries. Photothermal reduction of graphene oxide yields an expanded structure with micrometer-scale pores, cracks,...

متن کامل

Initial Discharge Capacity of Manganese Cobaltite as Anode Material for Lithium Ion Batteries

Nanostructured manganese cobalt oxide spinel (MnCo2O4) are prepared by co-precipitation method and calcined at 650 and 750°C. Morphological studies show that by increasing the calcination temperature from 650 to 750°C, morphology of the particles changes from quasi-plate to polyhedral. The MnCo2O4 calcined at 650°C could deliver an initial discharge capacity of 1438 mAh g-1 under current densit...

متن کامل

Silicon oxycarbide glass-graphene composite paper electrode for long-cycle lithium-ion batteries

Silicon and graphene are promising anode materials for lithium-ion batteries because of their high theoretical capacity; however, low volumetric energy density, poor efficiency and instability in high loading electrodes limit their practical application. Here we report a large area (approximately 15 cm × 2.5 cm) self-standing anode material consisting of molecular precursor-derived silicon oxyc...

متن کامل

High quality graphitized graphene as an anode material for lithium ion batteries.

High quality graphitized graphene has been successfully synthesized by solid-exfoliation of graphite and a subsequent wet chemical process. The as-obtained graphene exhibits charge-discharge behaviour quite different from that of reduced graphene oxide and shows enhanced cycling and rate performance compared with commercial mesocarbon microbeads (MCMBs) for lithium ion batteries.

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره 2  شماره 

صفحات  -

تاریخ انتشار 2015